This is, I believe, a general solution, though I tested it using IBM Informix Dynamic Server 11.50.FC3.  The following query:
SELECT grade,
       ROUND(100.0 * grade_sum / (SELECT COUNT(*) FROM grades), 2) AS pct_of_grades
    FROM (SELECT grade, COUNT(*) AS grade_sum
            FROM grades
            GROUP BY grade
         )
    ORDER BY grade;
gives the following output on the test data shown below the horizontal rule.  The ROUND function may be DBMS-specific, but the rest (probably) is not.  (Note that I changed 100 to 100.0 to ensure that the calculation occurs using non-integer - DECIMAL, NUMERIC - arithmetic; see the comments, and thanks to Thunder.)
grade  pct_of_grades
CHAR(1) DECIMAL(32,2)
A       32.26
B       16.13
C       12.90
D       12.90
E       9.68
F       16.13
CREATE TABLE grades
(
    id VARCHAR(10) NOT NULL,
    grade CHAR(1) NOT NULL CHECK (grade MATCHES '[ABCDEF]')
);
INSERT INTO grades VALUES('1001', 'A');
INSERT INTO grades VALUES('1002', 'B');
INSERT INTO grades VALUES('1003', 'F');
INSERT INTO grades VALUES('1004', 'C');
INSERT INTO grades VALUES('1005', 'D');
INSERT INTO grades VALUES('1006', 'A');
INSERT INTO grades VALUES('1007', 'F');
INSERT INTO grades VALUES('1008', 'C');
INSERT INTO grades VALUES('1009', 'A');
INSERT INTO grades VALUES('1010', 'E');
INSERT INTO grades VALUES('1001', 'A');
INSERT INTO grades VALUES('1012', 'F');
INSERT INTO grades VALUES('1013', 'D');
INSERT INTO grades VALUES('1014', 'B');
INSERT INTO grades VALUES('1015', 'E');
INSERT INTO grades VALUES('1016', 'A');
INSERT INTO grades VALUES('1017', 'F');
INSERT INTO grades VALUES('1018', 'B');
INSERT INTO grades VALUES('1019', 'C');
INSERT INTO grades VALUES('1020', 'A');
INSERT INTO grades VALUES('1021', 'A');
INSERT INTO grades VALUES('1022', 'E');
INSERT INTO grades VALUES('1023', 'D');
INSERT INTO grades VALUES('1024', 'B');
INSERT INTO grades VALUES('1025', 'A');
INSERT INTO grades VALUES('1026', 'A');
INSERT INTO grades VALUES('1027', 'D');
INSERT INTO grades VALUES('1028', 'B');
INSERT INTO grades VALUES('1029', 'A');
INSERT INTO grades VALUES('1030', 'C');
INSERT INTO grades VALUES('1031', 'F');