Template parameter of stxxl::vector is the type of contained items,
but std::vector is not a type, its missing it's template argument.
Try e.g. stxxl::vector<std::vector<int> >, or create
an enclosing template class around stxxl::vector if you want to
parametrize the itemtype of std::vector.
UPDATE:
After some research, I found this on the Stxxl: FAQ's first page
http://algo2.iti.kit.edu/stxxl/trunk/FAQ.html
Parameterizing STXXL Containers
STXXL container types like stxxl::vector can be parameterized only
  with a value type that is a POD (i. e. no virtual functions, no
  user-defined copy assignment/destructor, etc.) and does not contain
  references (including pointers) to internal memory. Usually, "complex"
  data types do not satisfy this requirements.
This is why stxxl::vector<std::vector<T> > and
  stxxl::vector<stxxl::vector<T> > are invalid. If appropriate, use
  std::vector<stxxl::vector<T> >, or emulate a two-dimensional array by
  doing index calculation.