The following transcript may prove illuminating:
32 ?- Term = (3*_X + 5*_Y = 10), functor(Term,F,A).
Term = 3*_G527+5*_G530=10
F = =
A = 2
33 ?- Term = (3*_X + 5*_Y = 10), arg(Arg,Term,Val).
Term = 3*_G459+5*_G462=10
Arg = 1
Val = 3*_G459+5*_G462 ; % user pressed ';' interactively
Term = 3*_G459+5*_G462=10
Arg = 2
Val = 10 ; % user pressed ';' interactively
No
35 ?- Term = (3*_X + 5*_Y = 10), arg(1,Term,Val1), functor(Val1,F1,A1),
arg(2,Val1,Val12).
Term = 3*_G693+5*_G696=10
Val1 = 3*_G693+5*_G696
F1 = +
A1 = 2
Val12 = 5*_G696
The last query reads: for Term as given, 1st arg of Term is Val1, the functor of Val1 is F1 with arity A1 (meaning, it has A1 args - subparts - itself), and 2nd arg of the term in Val1 is stored under Val12 name. To clarify, any symbolic data in Prolog is in the form of fff(aa,bb,cc,...) where fff is some name, called functor, and the "arguments" in that expression can be accessed through the arg call.
That means that the original expression (3*_X + 5*_Y = 10) is actually stored in Prolog as '='( '+'( '*'(3,_X), '*'(5,_Y)), 10). When you get to the atomic parts (functors with arity 0), you can check them further:
47 ?- arg(1,(3*X),V), functor(V,F,A), number(V).
X = _G441
V = 3
F = 3
A = 0
Yes
EDIT: to answer your other question (from the comments):
1 ?- (3*_X + 5*_Y = 10) = (A*X + B*Y = C).
A = 3
X = _G412
B = 5
Y = _G415
C = 10
Yes
If you insist on not writing out the multiplication sign * explicitly, you will have to represent your terms as strings, and to analyze that string. That would be a much more involved task.
EDIT: another thing to try is =.. predicate, called "Univ":
4 ?- (3*_X + 5*_Y = 10) =.. X.
X = [=, 3*_G454+5*_G457, 10]
Yes
5 ?- (3*_X + 5*_Y = 10) =.. X, X=[X1,X2,X3], X2 =.. Y.
X = [=, 3*_G545+5*_G548, 10]
X1 = =
X2 = 3*_G545+5*_G548
X3 = 10
Y = [+, 3*_G545, 5*_G548]
Yes