Answer:
public void Print(string FileName)
{
    StringBuilder logMessage = new StringBuilder();
    logMessage.AppendLine(string.Format(CultureInfo.InvariantCulture, "-------------------[ START - {0} - {1} -------------------]", MethodBase.GetCurrentMethod(), DateTime.Now.ToShortDateString()));
    logMessage.AppendLine(string.Format(CultureInfo.InvariantCulture, "Parameter: 1: [Name - {0}, Value - {1}", "None]", Convert.ToString("")));
    try
    {
        if (string.IsNullOrWhiteSpace(FileName)) return; // Prevents execution of below statements if filename is not selected.
        PrintDocument pd = new PrintDocument();
        //Disable the printing document pop-up dialog shown during printing.
        PrintController printController = new StandardPrintController();
        pd.PrintController = printController;
        //For testing only: Hardcoded set paper size to particular paper.
        //pd.PrinterSettings.DefaultPageSettings.PaperSize = new PaperSize("Custom 6x4", 720, 478);
        //pd.DefaultPageSettings.PaperSize = new PaperSize("Custom 6x4", 720, 478);
        pd.DefaultPageSettings.Margins = new Margins(0, 0, 0, 0);
        pd.PrinterSettings.DefaultPageSettings.Margins = new Margins(0, 0, 0, 0);
        pd.PrintPage += (sndr, args) =>
        {
            System.Drawing.Image i = System.Drawing.Image.FromFile(FileName);
            //Adjust the size of the image to the page to print the full image without loosing any part of the image.
            System.Drawing.Rectangle m = args.MarginBounds;
            //Logic below maintains Aspect Ratio.
            if ((double)i.Width / (double)i.Height > (double)m.Width / (double)m.Height) // image is wider
            {
                m.Height = (int)((double)i.Height / (double)i.Width * (double)m.Width);
            }
            else
            {
                m.Width = (int)((double)i.Width / (double)i.Height * (double)m.Height);
            }
            //Calculating optimal orientation.
            pd.DefaultPageSettings.Landscape = m.Width > m.Height;
            //Putting image in center of page.
            m.Y = (int)((((System.Drawing.Printing.PrintDocument)(sndr)).DefaultPageSettings.PaperSize.Height - m.Height) / 2);
            m.X = (int)((((System.Drawing.Printing.PrintDocument)(sndr)).DefaultPageSettings.PaperSize.Width - m.Width) / 2);
            args.Graphics.DrawImage(i, m);
        };
        pd.Print();
    }
    catch (Exception ex)
    {
        log.ErrorFormat("Error : {0}\n By : {1}-{2}", ex.ToString(), this.GetType(), MethodBase.GetCurrentMethod().Name);
    }
    finally
    {
        logMessage.AppendLine(string.Format(CultureInfo.InvariantCulture, "-------------------[ END  - {0} - {1} -------------------]", MethodBase.GetCurrentMethod().Name, DateTime.Now.ToShortDateString()));
        log.Info(logMessage.ToString());
    }
}