Installing more RAM is as simple as just plugging it to the motherboard and powering on the computer. You don't adjust anything from the operating system. The most you may be required to do is to enter the BIOS/UEFI and configure clock speed and timings.
Ideally you have to check your current RAM specs (clock speed and latency timings) and buy another stick with the same specifications. It's often preferable to get an identical stick (same vendor, same exact model) but in practice that's not required.
Also, the memory chips don't have to be necessarily the same size. Modern ASUS motherboards have this to say in the manual (but check your motherboard first):
You may install varying memory sizes in Channel A and Channel B. The
system maps the total size of the lower-sized channel for the
dual-channel configuration. Any excess memory from the higher-sized
channel is then mapped for single-channel operation
Also it is possible to setup dual-channel with different clock speeds with most motherboards I've seen. But this causes all of the memory to run at the speed of the slower one. And it may introduce stability issues.
The ASUS manual also says:
Always install DIMMs with the same CAS latency. For optimum
compatibility, we recommend that you obtain memory modules from the
same vendor.
To read more about RAM timings, read here: Calculate performance of RAM using timing and speed. Additionally, see Is it safe to use RAM sticks with different frequencies?.