Negative answer : Not possible (unless you can modify the
source-code of pacman).
The reason the option you're asking for was never added, is perhaps
that if the mirrors are not in sync, the user will end up with a mess.
The rational behind the current implementation option was probably
that it was only intended so that large packages will not block
the downloading of small ones.
I note that if the chosen (one) mirror limits the download speed of
its connections, usually opening multiple connections to the same
target can overcome this limitation.
However, if the download speed from the mirror is satisfactory with
one connection, choosing ParallelDownloads might even slow-down
the download, because each of the several connections will share
bandwidth with the others, and their competition over the local and
network resources will only waste time and prevent the connections
from reaching maximal bandwidth.