Although passwords can be used for both authentication and encryption, that does not hold true for all methods of authentication.
Decryption is reversing a transformation done based on some (secret) data, and the only way to do that is with the exact same data. Authentication, on the other hand, is verifying that the supplied piece of data (password / fingerprint / etc.) matches the one registered.
It can be determined that an image of a fingerprint is of the same finger as the one used to enroll, but the images won't be exactly the same. So if you would encrypt your GPG key with the data from a fingerprint image, you wouldn't be able to decrypt it using another image, even if we know it is of the same finger.