At the moment I cannot format the page number to be 2 digits in Microsoft Word 2010.
If you know how to, please share. Thank you!
Below is my screenshot.

At the moment I cannot format the page number to be 2 digits in Microsoft Word 2010.
If you know how to, please share. Thank you!
Below is my screenshot.

Right click the page number and select Toggle Field Codes.

Field codes of
{PAGE \# "00"}
{NUMPAGES \# "00"}
will give you page numbers with two digits. Now, press F9 or select Update Field to display the result.
More information: Insert and format field codes in Word 2010