Example
The option you need is -compression_algo with a value of raw or 1:
ffmpeg -i input -compression_algo raw -pix_fmt rgb24 output.tiff
As for the reason for the -pix_fmt rgb24 option see answer to Use ffmpeg for JPEG to TIFF conversion.
Private options
You can view information and options specific to each encoder (also called "private options"):
$ ffmpeg -v error -h encoder=tiff
Encoder tiff [TIFF image]:
Threading capabilities: frame
Supported pixel formats: rgb24 pal8 gray ya8 gray16le monob monow yuv420p yuv422p yuv440p yuv444p yuv410p yuv411p rgb48le rgba rgba64le
TIFF encoder AVOptions:
-dpi <int> E..V.... set the image resolution (in dpi) (from 1 to 65536) (default 72)
-compression_algo <int> E..V.... (from 1 to 32946) (default 32773)
packbits E..V....
raw E..V....
lzw E..V....
deflate E..V....