While my original answer missed the point (by trying to solve this problem with the solution to Accessing key in factory of defaultdict), I have reworked it to propose an actual solution to the present question.
Here it is:
class walkableDict(dict):
  def walk(self, callback):
    try:
      for key in self:
        self[key] = callback(self[key])
    except TypeError:
      return False
    return True
Usage:
>>> d = walkableDict({ k1: v1, k2: v2 ... })
>>> d.walk(f)
The idea is to subclass the original dict to give it the desired functionality: "mapping" a function over all the values.
The plus point is that this dictionary can be used to store the original data as if it was a dict, while transforming any data on request with a callback.
Of course, feel free to name the class and the function the way you want (the name chosen in this answer is inspired by PHP's array_walk() function).
Note: Neither the try-except block nor the return statements are mandatory for the functionality, they are there to further mimic the behavior of the PHP's array_walk.